P450-catalyzed reactions in which hydroperoxo-iron may function as an alternate electrophilic oxidant
| Reaction | Substrates |
|---|---|
| Decarbonylation | Aldehydes and ketones |
| Sulfoxidation | Thioethers |
| N-oxygenation | Amines |
| Epoxidation | Olefins |
| Hydroxylation of electron-rich aromatics | Phenols, anilines |
| Ipso-substitution | Halogenated phenols |
| Cyano oxidation | Nitriles |