Acyl Migration | Hydrolysis | Mutarotation | ||||||
---|---|---|---|---|---|---|---|---|
R | S | R | S | R | S | |||
1β→2β | 1.04 ± 0.158 | 0.52 ± 0.029 | 1β→KP | 0.03 ± 0.005 | 0.04 ± 0.005 | 2β→2α | 3.53 ± 0.462 | 4.50 ± 0.866 |
2β→3β | 0.25 ± 0.040 | 0.29 ± 0.059 | 2β→KP | 0.01 ± 0.002 | 0.01 ± 0.001 | 2α→2β | 3.17 ± 0.416 | 3.93 ± 0.723 |
2α→3α | 0.24 ± 0.025 | 0.14 ± 0.069 | 2α→KP | 0.01 ± 0.005 | 0.01 ± 0.003 | 3β→3α | 2.83 ± 0.289 | 3.97 ± 0.666 |
3β→2β | 0.18 ± 0.021 | 0.17 ± 0.047 | 3β→KP | 0.01 ± 0.001 | 0.01 ± 0.004 | 3α→3β | 3.07 ± 0.252 | 4.27 ± 0.839 |
3α→2α | 0.19 ± 0.023 | 0.11 ± 0.058 | 3α→KP | 0.01 ± 0.001 | 0.01 ± 0.001 | 4β→4α | — | 3.47 ± 0.681 |
3β→4β | — | 0.14 ± 0.021 | 4β→KP | — | 0.01 ± 0.002 | 4α→4β | — | 3.90 ± 0.608 |
3α→4α | — | 0.21 ± 0.006 | 4α→KP | — | 0.01 ± 0.001 | |||
4β→3β | — | 0.21 ± 0.029 | 4αβ→KP | 0.02 ± 0.013 | — | |||
4α→3α | — | 0.29 ± 0.035 | ||||||
3β→4αβ | 0.11 ± 0.023 | — | ||||||
3α→4αβ | 0.11 ± 0.012 | — | ||||||
4αβ→3β | 0.11 ± 0.012 | — | ||||||
4αβ→3α | 0.10 ± 0.000 | — |
↵2-a Values are means ± standard deviations of triplicate experiments.