A | B | C | D | E | F | G | H | I | |
---|---|---|---|---|---|---|---|---|---|
WIN in CDCl3 | 7.575 | 7.536 | 7.987 | 7.927 | 7.510 | 7.438 | 8.077 | 6.431 | 6.828 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
dd | t | dd | d | td | td | d | d | t | |
J a,b= 8.0 Hz | J = 8.0 Hz | J b,c = 8.0 Hz | J = 8.0 Hz | J d,e =J f,e = 8.0 Hz | J f,e =J f,g = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | |
J a,c = 1.2 Hz | J a,c = 1.2 Hz | J e,g = 1.2 Hz | J d,f = 1.2 Hz | ||||||
WIN in CD3OD | 7.524 | 7.453 | 7.899 | 8.012 | 7.576 | 7.622 | 8.054 | 6.480 | 6.828 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
d | t | d | d | t | td | d | d | t | |
J= 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J f,e = J f,g = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | |
M4 in CDCl3 | 7.361 | 7.316 | 7.899 | 4.873 | 4.561 | 5.916 | 6.568 | 6.483 | 6.899 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
d | t | d | d | d | dd | d | dd | t | |
J= 7.8 Hz | J = 7.8 Hz | J = 7.8 Hz | J = 10.4 Hz | J = 10.4 Hz | J g,f = 10 Hz | J = 10 Hz | J h,i = 8.0 Hz | J = 7.8 Hz | |
J f,e = 2.4 Hz | J h,j = 1.6 Hz | ||||||||
M4 in CD3OD | 7.249 | 7.415 | 7.782 | 4.809 | 4.409 | 5.905 | 6.410 | 6.620 | 6.912 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
dd | t | d | d | dd | dd | dd | d | t | |
J a,b= 7.8 Hz | J = 7.8 Hz | J = 7.8 Hz | J = 10.4 Hz | J d,e = 7.8 Hz | J g,f = 10 Hz | J g,f = 10 Hz | J = 8.0 Hz | J = 8.0 Hz | |
J a,c = 1.0 Hz | J e,f = 2.4 Hz | J f,e = 2.4 Hz | J g,e = 10 Hz | ||||||
M5 in CDCl3 | 4.996 | 4.670 | 6.224 | 7.220 | 7.247 | 7.345 | 7.662 | 7.304 | 7.008 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
d | dd | d | d | t | t | d | d | t | |
J= 10.8 Hz | J a,b = 10.8 Hz | J = 2.4 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | |
J b,c = 2.4 Hz | |||||||||
M5 in CD3OD | 4.875 | 4.532 | 6.110 | 7.093 | 7.187 | 7.337 | 7.717 | 7.347 | 7.010 |
1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | 1H | |
d | dd | d | d | t | t | d | d | d | |
J= 10.8 Hz | J a,b = 10.8 Hz | J = 2.4 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | J = 8.0 Hz | |
J b,c = 2.4 Hz |
J | Ka | Kb | L | Ma | Mb | N,Q | O,P | R |
---|---|---|---|---|---|---|---|---|
6.635 | 4.844 | 4.219 | 4.469 | 2.761 | 2.502 | 2.568 | 3.725 | 2.594 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
d | J ka,kb = 11.6 Hz | J ka,kb = 11.6 Hz | br-s | m | m | m | m | s |
J = 8.0 Hz | J k,l = 2.4 Hz | J k,l = 1.6 Hz | ||||||
6.615 | 4.848 | 4.217 | 4.769 | 2.724 | 2.539 | 2.505 | 3.606 | 2.483 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
d | J ka,kb = 11.6 Hz | J ka,kb = 11.6 Hz | br-s | m | m | m | m | s |
J = 8.0 Hz | J k,l = 2.4 Hz | J k,l = 1.6 Hz | ||||||
6.657 | 4.830 | 4.202 | 4.450 | 2.754 | 2.478 | 2.553 | 3.718 | 2.618 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
dd | J ka,kb = 11.6 Hz | J ka,kb = 11.6 Hz | br-s | m | m | m | m | s |
J i,j = 8.0 Hz | J k,l = 2.4 Hz | J k,l = 1.6 Hz | ||||||
J h,j = 1.6 Hz | ||||||||
6.640 | 4.819 | 4.213 | 4.779 | 2.730 | 2.485 | 2.542 | 3.692 | 2.557 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
dd | J ka,kb = 11.6 Hz | J ka,kb = 11.6 Hz | br-s | m | m | m | m | s |
J i,j = 8.0 Hz | J k,l = 2.4 Hz | J k,l = 1.6 Hz | ||||||
J h,j = 1.2 Hz | ||||||||
6.685 | 4.832 | 4.201 | 4.437 | 2.751 | 2.474 | 2.540 | 3.732 | 2.709 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
d | J ka,kb = 11.6 Hz | dd | br-s | m | m | m | m | s |
J = 8.0 Hz | J k,l = 2.4 Hz | J ka,kb = 11.6 Hz | ||||||
J k,l = 1.6 Hz | ||||||||
6.665 | 4.809 | 4.217 | 4.794 | 2.718 | 2.504 | 2.557 | 3.685 | 2.735 |
1H | 1H, dd | 1H, dd | 1H | 1H | 1H | 4H | 4H | 3H |
d | J ka,kb = 11.6 Hz | J ka,kb = 11.6 Hz | br-s | m | m | m | m | s |
J = 8.0 Hz | J k,l = 2.4 Hz | J k,l = 1.6 Hz | ||||||
br-s, broad singlet; d, doublet; dd, doublet of doublets;J, coupling constant in Hz; m, multiplet; s, singlet; t, triplet; td, doublet of triplet. Reference: CHCl3/δ 7.26 ppm; CHD2OD/δ 3.35 ppm.