Retention times and electron ionization mass spectral data of TMCU and its metabolites as obtained using GC/MS
Metabolite | Retention Time | Highest m/z Ion | Five Most Abundant m/z Ions | |
|---|---|---|---|---|
| min | % abundance | |||
| TMCU | 9.2 | 184(1.6), M+ | 169(45), 126(40), 97(57), 81(44), 55(100) | |
| OH-TMCU | 12.4 | 169(15), M+–CH2OH | 152(46), 126(43), 97(53), 81(100), 55(93) | |
| Trimethylsilylated OH-TMCU | 11.6 | 257(1), M+–CH3 | 215(9), 169(18), 130(54), 115(62), 73(100) | |
| Permethylated OH-TMCU | 10.4 | 256(0.1), M+ | 225(16), 142(74), 95(31), 85(29), 72(100) | |
| TMCU sulfate | 14.5 | 280(5), M+ | 109(19), 95(46), 81(74), 67(100), 55(72) | |
| Trimethylsilylated TMCU sulfate | 15.4 | 352(1), M+ | 129(31), 81(48), 75(100), 67(63), 55(52) | |
| Permethylated TMCU glucuronide | 25.0 | 460(1), M+–CH3 | 232(89), 201(100), 141(46), 116(51), 101(48) | |