| min | nm | | | | | |
M0 | 39.9 | <190 | 437.3402a, 455.3534, 583.3982, 601.4083,745.4511, 763.4635,803.4572, 819.4267 | 779.4593, 815.4310, 825.4654a, 842.4867, 893.4467 | [763.4635] → 745.4532, 601.4123, 583.3985, 455.3514, 437.3403a, 419.3329 | [825.4654] → [779.4566a]→ [617.4067a] → 541.3513, 471.3464a, 439.3207 | SSab |
[455.3534] → 437.3398, 425.3399, 419.3295, 407.3296, 401.3224, 389.3199, 299.2361, 285.2213, 283.2049, 267.2123, 265.1946, 253.1961, 251.1805, 241.1945, 239.1811, 233.1897, 231.1755, 223.1689, 215.1789, 213.1648, 205.1584, 201.1634, 187.1484a | |
M13 | 22.9 | <190 | 821.4632 | 797.4706 | | [797.4706] → [635.4135a] → 559.3655, 471.3479a, 439.3214 | HOSSc |
843.4772a | |
M14 | 15.2 | <190 | 819.4527 | 795.4561 | | [795.4561] → [633.3976a] → 557.3457, 487.3436a, 455.3172 | Monooxidation of SSa |
841.4623a |
M15 | 23.3 | <190 | 819.4512 | 795.4553 | | [795.4553] → [633.3995a] → 487.3436a | Monooxidation of SSa |
841.4609a |
M1 | 45.5 | <190 | 437.3425a | 617.4076 | [455.3541] → 285.2224, 267.2106, 223.1687, 205.1587, 187.1478a | [617.4076a] → 541.3523, 471.3485a, 439.3222 | PSGfc |
455.3541, 601.4077 | 663.4124a | |
M16 | 16.5 | <190 | 657.3997 | 633.4018 | | [633.4018] → 557.3489, 487.3447a, 455.3178 | Monooxidation of PSGf |
679.4031a |
M17 | 24.5 | <190 | 657.3968 | 633.4029 | | [633.4029] → 487.3440a, 455.3144 | Monooxidation of PSGf |
679.4047a |
M2 | 48.3 | <190 | 437.3411a, 455.3527 | 517.3513a | [455.3527] → 285.2210, 267.2118, 223.1703, 205.1597, 187.1497a | | SGfc |
|
M3 | 52.3 | <190 | 435.3271a | | [453.3378] → 423.3273a, 393.3140, 285.2207, 267.2109, 233.1896, 221.1550, 215.1792, 203.1428, 175.1479 | | Δ1-SGf |
453.3378, 493.3279 | |
M4 | 53.7 | <190 | 435.3254a, 453.3372 | | [453.3372] → 285.2217, 267.2114, 221.1536, 203.1443a, 185.1335 | | 3-keto-SGf |
M5 | 18.6 | <190 | 453.3369a, 471.3457 | 533.3499a | [471.3457] → 249.1861, 231.1739, 223.1697, 213.1651, 205.1601, 187.1489a | | Hydroxylation of SGf |
M6 | 26.0 | <190 | 453.3361a, 471.3469 | 533.3467a | [471.3469] → 453.3387a | | Hydroxylation of SGf |
[453.3361] → 229.1584, 223.1693, 211.1477, 205.1591, 187.1487a |
M7 | 18.4 | <190 | 467.3153a, 485.3250 | 501.3234a | [485.3250] → 455.3161, 263.1656, 245.1533, 231.1374, 223.1692, 205.1594, 199.1493, 187.1482a | [501.3234] → 453.2987a, 437.3038 | SGf-27-oic acid |
M8 | 42.2 | <190 | 467.3167a, 485.3273 | 501.3238a | [485.3273] → 253.1451, 235.1340, 233.1907, 217.1224, 215.1805, 171.1169a | [501.3238] → 453.2991a, 437.3044 | Carboxylation and hydroxylation of SGf |
M9 | 27.0 | <190 | 467.3158a, 485.3259 | 501.3217a | [485.3259] → 467.3140a | [501.3217] → 453.3016a, 437.3069 | Unidentified |
[467.3158] → 449.3050a, 431.2941 | |
M10 | 14.7 | <190 | 483.3098a, 501.3199 | 517.3171a | [501.3199] → 253.1447, 249.1867, 235.1345, 231.1743, 217.1235, 213.1635, 171.1167a | [517.3171] → 469.2965a, 453.3023 | Carboxylation and hydroxylation of SGf |
M11 | 19.6 | <190 | 483.3104a, 501.3204 | 517.3152a | [501.3199] → 483.3127a | [517.3152] → 469.2932a, 453.2989 | Unidentified |
[483.3104] → 465.3021a | |
M12 | 30.2 | <190 | 483.3123a, 501.3207 | 517.3184a | [501.3207] → 483.3087a | [517.3184] → 469.2936a, 453.2991 | Unidentified |
[483.3123] → 465.2983a | |