Abstract
Seven structure analogical flavonoid aglycones have been analyzed using electrospray ionization tandem mass spectrometry (ESI-MSn) in the negative-ion mode. The spectra obtained ESI-MSn allowed us to propose plausible schemes for their fragmentation mechanism. By analyzing the product ions spectra of deprotonated molecule ions [M–H]−, some neutral diagnostic losses and specific retro Diels–Alder fragments were obtained. By using all of these characteristic fragment ions we can specially differentiate the flavone isomer.
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Wu, W., Liu, Z., Song, F. et al. Structural Analysis of Selected Characteristic Flavones by Electrospray Tandem Mass Spectrometry. ANAL. SCI. 20, 1103–1105 (2004). https://doi.org/10.2116/analsci.20.1103
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DOI: https://doi.org/10.2116/analsci.20.1103