Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization (CLRP)
technique that enables the design of well-defined, functional and complex macromolecular …

… The complete kinetic scheme (Scheme 2) is composed of 3 stages, with k d and k d,ds the
homolysis rate constants of the initiator R 1 R 2 NOR (eqn (4)) and of the dormant species ds (…

… The potential window was 3.8 V to 2.5 V for regimes below C/2; the lower potential limit is
decreased to 2 V at D and 1.5 V at 2C. The charge is always C/15 unless specified otherwise …

The development of nanoscale masking for particle deposition is exceedingly important to
push the future of nanoelectronics beyond the current limits of lithography. We present the first …

… , we can deduce the mean distance D between the center of masses of the particles in the
real space using the relation Q* = 2π/D. The resulting calculated distance D = 314 Å is close to …

… a k d, T C was estimated using the E a values and a frequency factor of 2.14 × 10 14 s -1 .
b Assuming a very weak effect of the penultimate unit (ca. 1 kJ mol -1 ), E a of S−MMA−SG1 is …

A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)oxy)amino)-2-methylpropanoate
4) bearing a chromophore group directly linked to the …

… (D) Sanger sequencing output showing a K27M mutation (arrow), the most frequent … Jones
C, Perryman L, Hargrave D. Paediatric and adult malignant glioma: close relatives or distant …

… Our results highlight the pivotal role of the k d values of the initiating alkoxyamine, that is,
successful NMP experiments depend on the k p /k d1 ratio (eq 15) and that it should be …

… As k c is only weakly dependent on the temperature, we can determine the optimized k d
value for having a living and controlled polymerization. The knowledge of the activation energy …